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Having tried similar things, I cannot stress enough how much you want to be printing molds like this in TPU unless you really really want your mold to be permanently embedded in the concrete
Pla and a heatgun works but its not ideal. Definitely takes a while to melt off from more complex geometries akd isnt reusable.
In theory ABS is acetone soluable but ive been having a hard time coming up with a usecase where acetone is preferable to anything else